toplevel vars added by syntax expansion are unbound

toplevel vars added by syntax expansion are unbound

* module/ice-9/psyntax.scm (chi-top): When adding to the toplevel
  environment at compile-time, default to undefined variables, not
  variables defined to #f.

* module/ice-9/psyntax-pp.scm: Regenerate.

* module/ice-9/boot-9.scm (module-add!): Add a new pre-modules version
  of this function, so we can add variables the environment, not just
  values.
  (module-define!): Use module-add!.